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The small cell-volume expansion associated with the formation of the lead-deficient phase is 0.52%, leading to a volumetric expansion of 0.13%. The structure of Pb(0.167)TeI has been determined using powder X-ray diffraction data. The lattice parameters of the structure can be described by a pseudo-orthorhombic supercell and PbTeI is built up from dimers with a Pb-Te-Pb connectivity along the a-axis of the supercell. The crystal structure of the lead-deficient phase has been refined with a space group of C2/c with a primitive cell containing one formula unit. The structure of PbTeI has been determined using single-crystal X-ray diffraction data. The second phase has a structure composed of planes of corner-sharing Te-Pb-Te octahedra with all Pb ions in a cationic position, and this phase has been designated as Pb(0.167)TeI. 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